Ref. No. : CA - 18937 - (Quality - Resin, Compounds, Masterbatch – with 14.6 years in Plastic Industry)

Education

Doctor of Philosophy (Ph.D), Chemistry From Osmania University, Hyderabad, India Research work carried out at Indian Institute of Chemical Technology (IICT), Hyderabad, India in 2012

Master of Technology (M.Tech), Surface Science & Engineering From National Institute of Technology, Jamshedpur, India in 2005

Master of Science (M.Sc), Organic Chemistry From Berhampur University, Orissa, India in 2000

Bachelor of Science (B.Sc), Chemistry From Berhampur University, Orissa, India in 1998

Skill Sets

Polymer Synthesis; Characterization; Spectral Analysis; Literature and Patent Search; Documentation & Presentation

Instrumental Skills:
1H and 13C NMR, Dynamic Mechanical Thermal Analyzer (DMTA IV; Rheometric Scientific Inc; Piscataway, NJ, USA), Differential Scanning Calorimeter (DSC; Mettler Toledo 821), Thermogravimetric Analyzer (Mettler Toledo TGA/SDTA 851 and Parkin Emler 7), X-ray photoelectron spectroscopy (ESCA; Kratos Axis 165; Manchester, UK), SEM Hitachi-S520 (Oxford Link ISIS-SEM model), Fourier Transformed Infrared Spectrophotometer (FTIR; Nicolate Nexus spectrometer). Pull-off Adhesion Test (Microtech Tensiometer, UK), Abrasion Resistance (Taber, USA), Impact, Flexibility by Conical Mendril Test, Scratch Resistance, Pencil Hardness, Salt Spray.

Work Experience

Deputy Manager, Technical & Development 
Since March 2012
Company Profile: Composite Division, involved in manufacturing and molding of Unsaturated Polyester/Vinyl Ester resin based molding compounds Sheet Molding Compounds (SMC) and Bulk Molding Compounds (BMC) for automotive and electrical applications
Job Profile:
Quality inspection of raw materials/finished products and their timely delivery to production line and customer end
Generation of ideas for new product development
Implementation of the idea starting from prototype to pilot batch
Physical & mechanical characterization of composites
New product developments
Managing a R & D team and monitoring their day to day activity

Projects Handled:
Development of light weight auto components with improved property using nano CaCO3 for better fuel efficiency and CO2 emission [Completed]
Development of tough hybrid resin for crack free Sheet Molding Composites (SMC) [Completed]
Development of weatherable SMC with homogeneous pigmentation [Under progress]
Development of peroxide free SMC [Under progress]

Senior Research Scientist, R & D Center
Jul - 2011 to Mar - 2012
Company Profile: manufacturing Chlorinated Paraffin Oi
Job Profile:
Quality inspection of raw materials/finished products and their timely delivery to the customer
Generation of new ideas for product improvement
Managing a R & D team
Planning of regular lab activity for the team
Training given to the employee regarding 5S and safety

Research Experience:
Polymer Synthesis and Characterization
Structure-Property Relation
Nanocomposite
Surface Modification
High Performance Coatings
Fiber Reinforced Composite [Sheet Molding Compounds (SMC)/ Bulk molding Compounds (BMC)/Pultrusion/Resin Transfer Molding (RTM) etc.]
Natural Fiber & Bio Composites


Synopsis Of Ph.d Work:
In past two decades both the dendrimers and hyperbranched polymers (HBPs) have attained increased interest due to their unique structure and unusual properties. The dendrimers are monodisperse [Degree of branching (DB) =1] and highly symmetrical while, the HBPs are polydispersity [DB<1], and unsymmetrical. The synthesis of dendrimer is quite tedious job and requires several protection and deprotection steps as well as extensive purifications between the successive generations. Their synthesis is not only expensive, but also restrictive for the use in material-consuming applications due to the lower yields. The difficulty in synthesis of dendrimers has made the use of HBPs, as the only solution of using branched architecture in a cost-effective way to produce polymers for large scale applications. HBPs possesses properties almost similar to that of dendrimers such as; highly branched structure, large number of reactive end groups, excellent flow and processing characteristics due to lower amount of inter or intramolecular entanglements and globular structure. Thus, HBPs were chosen as unique alternative with almost similar properties to that of dendrimers. The lower viscosity at high molecular weight of these HBPs is an important criteria for the development of High solid coatings with improved properties.
In my doctoral research, I have prepared different aromatic and aliphatic hydroxyl terminated hyperbranched polyester polyols (HBPs) and used those as precursors for the synthesis of hyperbranched polyurethane (HBPU)-urea, HBPU-imide, HBPU-urea/o-clay, HBPU-imide/o-clay and HBPU-urea-imide/o-clay-silica hybrid coatings by using different methodologies. The different methodologies are described below.
Methodology : Moisture curable HBPU coatings
Methodology : Different chain extender based HBPU coatings
Methodology : Inorganic-organic hybrid coatings based on o-clay
Methodology : APTMS grafted o-clay based inorganic-organic hybrid coatings
Methodology : HBPU-urea coating using click chemistry
Methodology : High Sold UV curable & Water-borne Coating

Awards & Fellowships:
Qualified Graduate Aptitude Test in Engineering (GATE) 2000 in Chemistry with 86.74 percentile conducted by the IISc, Bangalore, India
Senior Research Fellow (SRF) 2007-2011, in Material Science by Council of Scientific & Industrial Research (CSIR), New Delhi, India 

Training:
Attended an entrepreneurship program conducted by CSIR, New Delhi, India
8D, 5S and KAIZEN
7 QC Tools (Problem solving)
SPC (Statistical Process Control)
Assertiveness Skill
Effective Problem Solving Techniques
ISO 9001/TS Awareness
Team Engagement

Publications:
Synthesis & charecterizationof benzaldehyde modified acetoacetylated 
polyesters for Polyurethane/Urea Coatings 
Allauddin, S.; K. K. Jena.; Mishra, A. K.; Radhika, K. R.; Narayan, R.; 
Raju, K. V. S. N. Prog.Org. Coat, 2012, In press 

Hyperbranched Polyurethane-urea-imide/o-clay-silica Hybrids: Synthesis and Characterization
Mishra, A. K.; Narayan, R.; Aminabhavi, T. M.; Pradhan, S. K.; Raju, K.V.S.N. 
J. Appl. Polym. Sci., 2012, 125, E67-E75 

Hyperbranched polyurethane (HBPU)-urea and HBPU-imide coatings: Effect of chain extender and NCO/OH ratio on their properties
Mishra, A. K.; Narayan, R.; Aminabhavi, T. M.; Raju, K.V.S.N. 
Prog. Org. Coat, 2012, 74(1), 134-141

Characterization of surface-modified montmorillonite nanocomposites
Mishra, A. K.; Allauddin, S.; Narayan, R.; Aminabhavi, T. M.; Raju, K.V.S.N. 
Ceramics International, 2012, 38(2), 929-934

Synthesis of Triazole ring containing Pentol Chain Extender and its Effect on the Properties of Hyperbranched Polyurethane-Urea Coatings
Priyanka K. G, Mishra, A. K.; Kantheti, S.; Narayan, R.; Raju, K. V. S. N.  
J. Appl. Polym. Sci., 2012, In press

Structure property correlation study of HBPU coatings
Mishra, A. K.; Narayan, R.; Aminabhavi, T. M.; Raju, K.V.S.N. 
Prog. Org. Coat, 2012, 74(3), 491-501

Effect of NCO/OH ratio and Ce-Zr nanoparticles on the thermo-mechanical properties of hyperbranched polyurethane urea coatings 
Mishra, A. K.; Allauddin, S.; Radhika, K. R.; Narayan, R.; Raju, K. V. S. N. Polym. Adv. Technol. 2011, 22(6), 882-890

Effect of nano ZnO on the phase mixing of polyurethane hybrid dispersions Mishra, A. K.; Mishra, R. S.; Narayan, R.; Raju, K.V.S.N. 
Prog. Org. Coat. 2010, 67, 405-413
             
Synthesis and characterization of hyperbranched polyester–urethane–urea/K10-clay hybrid coatings
Mishra, A. K.; Jena, K. K.; Raju, K.V.S.N.  
Prog. Org. Coat. 2009, 64, 47-56  

Synthesis and property study of UV-curable hyperbranched polyurethane acrylate/ZnO hybrid coatings                         
Mishra, R. S.; Mishra, A. K.; Raju, K.V.S.N. 
Eur. Polym. J. 2009, 45, 960-966

Thermal and Thermomechanical Properties of Hyperbranched Polyurethane-Urea/Cenosphere Hybrids 
Jena, K. K.; Mishra, A. K.; Raju, K.V.S.N. 
J. Appl. Polym. Sci. 2008, 110, 4022–4033 

Synthesis and characterization of hyperbranched polyesters and polyurethane coatings               Mishra, A. K.; Chattopadhyay, D. K.; Raju, K. V. S. N. 
J. Polym. Sci. Part A: Polym. Chem. 2007, 45, 2673-2688

Organically modified montmorillonite hyperbranched polyurethane–urea hybrid composites Kumari, S.; Mishra, A. K.; Krishna, A.V.R.; Raju, K.V.S.N.
Prog. Org. Coat. 2007, 60, 54-62

FT-IR and XPS studies of polyurethane-urea-imide coatings
Mishra, A. K.; Chattopadhyay, D. K.; Sreedhar, B.; Raju, K.V.S.N. 
Prog. Org. Coat. 2006, 55, 231-243

Thermal and dynamic mechanical characterization of polyurethane-urea-imide coatings               Mishra, A. K.; Chattopadhyay, D. K.; Sreedhar, B.; Raju, K.V.S.N. 
J. Appl. Polym. Sci. 2006, 102, 3158-3167 

Thermal and viscoelastic properties of polyurethane-imide/clay hybrid coatings 
Chattopadhyay, D. K.; Mishra, A. K.; Sreedhar, B.; Raju, K.V.S.N.
Polym. Degrd. Stab. 2006, 91, 1837-1849 

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